Chemical Reactions of Amines

IMPORTANT

Chemical Reactions of Amines: Overview

This topic covers concepts such as Alkylation of Amines, Acylation of Amines, Carbylamine Reaction, Reaction of Amines with Nitrous Acid, Reaction of Amines with Benzene Sulphonyl Chlorides, Nitration of of Aromatic Amines, etc.

Important Questions on Chemical Reactions of Amines

MEDIUM
IMPORTANT

Identify A, B, C and D in the following process :

(i)   C H 3 C H 2 Cl NaCN A Ni / H 2 reduction B

(ii)   C 6 H 5 N H 2   NaN O 2 / HCl C C 6 H 5 N H 2 / O H D

EASY
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The products of the following chemical reactions are,

    i C2H5NH2+C6H5SO2Cl

   ii C2H5NH2+HNO2

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The products of the following chemical reactions are

(i)  C2H5NH2+C6H5SO2Cl

(ii)  C2H5NH2+HNO2H2O

EASY
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Which of the following chemical test can distinguish between methylamine and dimethylamine?

EASY
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Which of the following chemical test can distinguish between methylamine and dimethylamine?

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The following pairs of computes can be distinguished by which of the following tests:

 (i) Ethylamine and aniline

(ii) Aniline and N-methylaniline

HARD
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The following pairs of compounds can be distinguished by which of the following tests:

(i) Ethyl amine and aniline

(ii) Aniline and N-methyl aniline

EASY
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The test that is done for the differentiation of primary amines from secondary and tertiary amine is:

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In the chemical reaction:
CH 3 CH 2 NH2+ CHCl 3 + 3 KOH A + B + 3 H 2 O , the compound (A) and (B) are respectively:

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In the following chemical reactions, the compounds A and B are respectively:

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EASY
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Aniline on heating with chloroform and alcoholic potassium hydroxide leads to the formation of

HARD
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In the following reaction sequence,

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the major products X and Z are

MEDIUM
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Nitrobenzene is obtained from benzene where HNO3 and H2SO4 takes part in the reaction. What is behaviour of HNO3 like-

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What are the compounds (B) and (C) in the following reaction?

C6H5NH2+CHCl3KOH(A) H+/H2O B +C

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In the following sequence of reactions
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The compound C formed will be

HARD
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Which of the following can be used to distinguish between primary, secondary and tertiary amines?

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Hinsberg reagent is:

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The product Y for the below reaction is:

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MEDIUM
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What are the compounds (B) and (C) in the following reaction?

C6H5NH2+CHCl3KOH(A) H+/H2O B +C